Getafe beat Celta Vigo 3-1 to move up to fifth in La Liga, one point behind Sevilla.
Lionel Messi's two goals were not enough for Barcelona to salvage a win as they were held to a 2-2 draw at home to Valencia.
Rodrigo scored twice in stoppage-time to fire Valencia to the Copa del Rey semi-finals with a 3-1 win over Getafe.
Atletico Madrid cut the gap to La Liga leaders Barcelona to two points as they beat Getafe 2-0 at the Wanda Metropolitano.
Jorge Molina's 77th-minute strike earned Getafe a 1-0 home Copa del Rey win over Valencia in a feisty quarter-final first-leg clash on Tuesday.
Two goals apiece from Jaime Mata and Jorge Molina gave Getafe a comprehensive 4-0 home victory against fellow European hopefuls Alaves.
Santi Mina struck twice as struggling Valencia reached the Copa del Rey quarter-finals by beating second-tier Sporting Gijon 3-0.
Borja Baston salvaged a point for Alaves in a 1-1 draw at Girona on Saturday but the visitors missed the chance to move up to third place in La Liga table.
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